Supramolecular Chirality in Dynamic Coordination Chemistry

نویسندگان

چکیده

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Supramolecular Chirality in Dynamic Coordination Chemistry

Labile metal complexes have a useful coordination bond; which is weaker than a covalent C–C bond and is reversibly and dynamically formed and dissociated. Such labile metal complexes also can be used to construct chiral shapes and offer dynamic conversion of chiral molecular shapes in response to external stimuli. This review provides recent examples of chirality induction and describes the dyn...

متن کامل

Supramolecular Chirality in Porphyrin Chemistry

Supramolecular chirality, being an intelligent combination of supramolecular chemistry and chiral science, plays a decisive role in the functioning of various natural assemblies and has attracted much attention from the scientific community, due to different applications in modern technologies, medicine, pharmacology, catalysis and biomimetic research. Porphyrin molecules are of particular inte...

متن کامل

Supramolecular coordination chemistry

Highlights include the formation of ultra-large macrocycles with over 200 non-hundred atoms within a given cycle. The realisation that single molecule magnetic behaviour is not limited to molecules with high spin states. The connection of S = 1/2 cluster rings using a fragment that can switch on magnetic exchange between the clusters is extremely interesting for the synthesis of QBITs and elect...

متن کامل

Supramolecular Chirality: Solvent Chirality Transfer in Molecular Chemistry and Polymer Chemistry

Controlled mirror symmetry breaking arising from chemical and physical origin is currently one of the hottest issues in the field of supramolecular chirality. The dynamic twisting abilities of solvent molecules are often ignored and unknown, although the targeted molecules and polymers in a fluid solution are surrounded by solvent molecules. We should pay more attention to the facts that mostly...

متن کامل

From supramolecular chemistry towards constitutional dynamic chemistry and adaptive chemistry.

Supramolecular chemistry has developed over the last forty years as chemistry beyond the molecule. Starting with the investigation of the basis of molecular recognition, it has explored the implementation of molecular information in the programming of chemical systems towards self-organisation processes, that may occur either on the basis of design or with selection of their components. Supramo...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Symmetry

سال: 2014

ISSN: 2073-8994

DOI: 10.3390/sym6040880